| Montanes - Marrero 6:0 6:1 | 1 s |
| Rakousko - Francie 2:3 | 2 s |
| Bartoli - Ivanovic 6:3 6:4 | 3 s |
| Gallovits - Chala 6:0 6:2 | 1 s |
| Falla - K.Beck 7:6(3) 6:4 | 2 s |
| Klizan - Vagnozzi 6:2 6:4 | 3 s |
| Zvonareva - Safina 6:4 7:6(6) | 2 s |
| Gil - F.Prpic 6:4 6:4 | 2 s |
| Fish - G.Simon 7:6(4) 7:5 | 1 s |
| Makarova - Dzehalevich 6:2 6:0 | 1 s |
| Camerin - Ferguson 6:4 6:0 | 3 s |
| Makarova - Bratchikova 6:2 5:7 6:2 | 2 s |
| Dodig - Schuettler 3:6 6:3 6:4 | 2 s |
| Capdeville - Junqueira 6:3 3:6 6:3 | 3 s |
| Kuznetsova - Kirilenko 3:6 6:2 4:6 | 2 s |
| Hercog - Sevastova 4:6 6:7(5) | 3 s |
| Martic - Georgatou 6:3 6:1 | 2 s |
| Baghdatis - Stakhovsky 7:5 1:6 6:7(4) | 2 s |
| Cuevas - Ilhan 2:6 2:6 | 3 s |
| Sharapova - Date 5:7 6:3 3:6 | 2 s |
| Bartoli - Camerin 6:0 6:1 | 1 s |
| Sugita - Lop.Jaen 6:1 6:0 | 2 s |
| Rodionova An. - Mchale 2:6 6:4 5:7 | 3 s |