 | Ferrero - Ljubicic 1:6 6:3 6:4 | 4 s |
| Karlovic - Becker Ben. 7:6(5) 6:4 | 6 s |
| Zeballos - Veic 6:7(6) 6:7(12) | 6 s |
| Zhang S. - Chang K. 6:4 6:7(3) 6:4 | 6 s |
| Serra F. - De Schepper 6:1 6:4 | 9 s |
| Kudla - Salamanca 2:6 2:6 | 7 s |
| Eaton - Margaroli 6:1 6:1 | 6 s |
| Kerber - Kudryavtseva 6:3 6:1 | 7 s |
| Fish - Haase 7:6(1) 6:2 6:1 | 6 s |
| Djokovic N. - Berdych 7:5 ret. | 6 s |
| Sijsling - Struff 7:6(2) 6:3 | 6 s |
| Balazs - Stadler 7:5 3:6 6:2 | 7 s |
| De Bakker - Duclos 6:4 2:6 6:4 | 7 s |
| Rodina - Savchuk 6:7(4) 6:2 1:6 | 6 s |
| Djokovic N. - Baghdatis 6:4 4:6 6:3 6:4 | 6 s |
| Cipolla - Červenák 6:1 6:2 | 6 s |
| Gajdosova - Marino 1:6 6:2 7:5 | 7 s |
| Haase - Vagnozzi 3:6 6:3 6:1 | 9 s |
 | Voskoboeva - Govortsova 6:3 6:4 | 6 s |
Trenéři
