| Chile - Australie(ctyr) 7:6(5) 6:7(8) 3:6 7:5 5:7 | 2 s |
| O.Hernandez - Gimeno Tra 6:1 6:2 | 4 s |
| Dancevic - Bogomolov 6:2 6:3 | 1 s |
| Strycova - Arn 6:7(3) 6:3 8:6 | 2 s |
| V.Der Merwe - Lopez Jaen 6:3 6:1 | 3 s |
| Llagostera - Gajdosova 6:0 6:3 | 2 s |
| Safarova - M.J.martinez 2:6 1:4 ret. | 4 s |
| Lisnard - D.Alvarez 6:1 6:2 | 2 s |
| Zheng - Sugiyama 6:1 6:2 | 3 s |
| Korolev - Golubev 6:3 6:3 | 3 s |
| Pennetta - Medina G. 6:3 7:6(6) | 3 s |
| Canas - Pashanski 6:7(3) 6:3 7:5 | 2 s |
| Sweeting - Ouanna 6:2 5:7 6:4 | 4 s |
| Luzhanska - J.Jackson 6:2 3:6 2:6 | 4 s |
| M.Daniel - Estrella 6:3 7:6(3) | 4 s |
| Andreev - O.Rochus 6:3 6:4 | 1 s |
| Morita - Lykina 6:1 6:3 | 2 s |
| Chakvetadze - Craybas 6:2 7:5 | 1 s |
| Dementieva - Bacsinszky 4:6 6:3 6:3 | 2 s |
| K.Kim - L.Gregorc 6:4 5:7 6:2 | 2 s |
| F.Gonzalez - Gulbis 4:6 7:6 (11) 6:1 | 2 s |
| Patience - Villagran 6:4 7:6(7) | 5 s |
| Goerges - Vrljic 4:6 2:4 ret. | 2 s |